|
|
1-(methylsulfanyl)-6-aci-nitrohexane + glutathione <=> (E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-11424
|
|
|
|
L-trihomomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> H2O + CO2 + oxidized_[NADPH-hemoprotein_reductase] + 6-Methylthiohexanaldoxime
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
|
MetaCyc:
RXNQT-4310
|
|
|
|
3''-phosphoadenylyl-sulfate + 5-(methylsulfanyl)pentyl-desulfoglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + 5-methylthiopentylglucosinolate
|
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
|
|
MetaCyc:
RXNQT-4330
|
|
|
|
(E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
|
MetaCyc:
RXN-11432
|
|
|
|
5-(methylsulfinyl)pentyl-glucosinolate + O2 <=> 4-pentenylglucosinolate + methanesulfonate + H+
|
1.14.11.M8
|
–
|
|
MetaCyc:
RXNQT-4344
|
|
|
|
6-Methylthiohexanaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-(methylsulfanyl)-6-aci-nitrohexane + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
|
MetaCyc:
RXN-11416
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)hexyl-thiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
|
MetaCyc:
RXN-11440
|
|
|
|
(E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)hexyl-thiohydroximate + pyruvate + NH3
|
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
|
|
MetaCyc:
RXNQT-4320
|
|
|
|
5-methylthiopentylglucosinolate + O2 + NADPH + H+ <=> 5-(methylsulfinyl)pentyl-glucosinolate + H2O + NADP+
|
1.14.13.237
aliphatic glucosinolate S-oxygenase
|
–
|
|
MetaCyc:
RXNQT-4335
|
|
|
|
UDP-glucose + (E)-omega-(methylsulfanyl)hexyl-thiohydroximate <=> H+ + 5-(methylsulfanyl)pentyl-desulfoglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
|
MetaCyc:
RXNQT-4325
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + H2O <=> (E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)hexan-1-imine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
|
MetaCyc:
RXN-19593
|
|